A hierarchical 3D hybrid CoAl-layered double hydroxide/TiO2/Ti3C2 MXene S-scheme photocatalyst with 2D/0D/2D contact interfaces for sustainable pollutant degradation

Abstract

Environmental pollution, particularly that derived from waterborne antibiotics, is a rising concern because of its detrimental effects on aquatic ecosystems and human health. Hence, in this study, we present a hierarchical 3D-structured hybrid photocatalyst comprising a CoAl-layered double hydroxide (LDH), TiO2, and Ti3C2 MXene synthesized using an in situ hydrothermal method. Various characterization techniques revealed that the hybrid CoAl-LDH/TiO2/Ti3C2 photocatalyst exhibited improved optical absorption, and the tailored 2D/0D/2D contact interfaces among the constituents enhanced charge migration and minimized electron-hole recombination. The results of electron paramagnetic resonance and in situ-irradiated X-ray photoelectron spectroscopy analyses confirmed that the hybrid photocatalyst follows an S-scheme mechanism that not only promotes the separation of photoinduced electron-hole pairs but also preserves their robust redox capability. The amalgamation of the three components resulted in synergistic advantages. Consequently, the optimized CoAl-LDH/TiO2/Ti3C2 photocatalyst exhibited remarkable performance in degrading and mineralizing the antibiotic diclofenac sodium (DFS) and the dyes rhodamine B and indigo carmine, surpassing its constituents and previously reported photocatalysts. Furthermore, the hybrid retained high efficiency across multiple cycles, underscoring its potential reusability. Therefore, this study demonstrates the potential of the developed hybrid photocatalyst for sustainable water treatment, thereby fostering cleaner aqueous environments.