A geopolymeric composite of non-calcined rice husks made of metakaolin/sol–gel silica

Abstract

In this work, the development of a composite material with geopolymer and a high content of rice husks without heat treatment was investigated to create and characterize a low-cost composite made with agro-industrial wastes. The ratio used was about 12/88 wt./% of sol–gel and metakaolin related to rice husks. This kind of composite geopolymer was designed as both a construction material for load or aesthetic finishing. X-ray diffraction studies reveal that the composite has an amorphous phase and a crystalline one, which is typical of geopolymeric materials. The scanning electron microscopy showed that the geopolymeric matrix completely wrapped the rice husks. The composite material has a compressive strength close to some mortars with a value of about 110 kg/cm2 (10.8 MPa). Laser scanning confocal microscopy reveals that there is a difference of emission in the visible spectrum between the inner and outer sides of the rice husks, which corroborates that they have a different chemical composition. Differential scanning calorimetry analysis confirmed that the composite material has combined characteristics of its raw materials. X-ray diffraction studies show that metakaolin with sol–gel solutions had temperature-dependent interactions besides that, after the dehydroxylation, the composite material is mostly amorphous. The material of high content of rice husk bound by geopolymer could be applicable in various areas of the construction industry and finishing.