Abstract
AbstractIn this study, we introduce two ortho‐carboranyl compounds, namely ICzCB and mTPCB, which exhibit different planarity in their appended π‐conjugated aromatic groups, to investigate the influence of geometric effects on the regulation of the radiative efficiency. Both the compounds are fully characterized, revealing distinct geometric differences (planarity) in their single‐crystal structures. While ICzCB presents strong ICT‐based emission in the solid (film) state, mTPCB displays dual emission in the high‐ and low‐energy regions that originates from locally excited (LE)‐ and ICT‐based processes, respectively. Quantitative analysis of the photophysical characteristics of the compounds shows that the ICT‐based radiative efficiency in ICzCB is higher than that in mTPCB. Consequently, these findings demonstrate that the planarity of the π‐conjugated aryl group appended on o‐carborane, which is represented by planar ICzCB and distorted mTPCB, is an important key to control the ICT‐based radiative decay efficiency.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
