Abstract
Combination of ( R )-4- t -butyldimethylsiloxy-2-cyclopentenone, ( S )-( E )-3- t -butyldimethylsiloxy-1-iodo-1-octene, and 6-methoxycarbonyl-2-hexynal via the tandem organo-copper conjugate addition—aldol reaction procedure leads directly to a 5,6-dehydroprostaglandin E 2 derivative, which can be transformed to a variety of chiral primary prostaglandins in a stereoselective manner.
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