Abstract
Kinetic equations for first, second, and third order reactions between organic molecules and hydrophilic ions in micellar solutions are derived. The approach depends upon the validity of two new assumptions. First, in accord with other recent treatments, rate enhancements are assumed to arise primarily from the large increase in the relative concentrations of the organic and hydrophilic substrates upon incorporation into the micellar phase. Second, the Stern layer of the micelle is assumed to be saturated with respect to its counterion.
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