Abstract
The molecular structure of trans-stilbene has been studied by the gas electron diffraction method. Unlike the approximately planar structure with C i symmetry found for the solid state, the molecule in the gas phase was found to be non-planar and to possess C 2 symmetry. The phenyl groups were found to be rotated ca. 30° about the C-φ bonds. The non-planarity of the molecule is, however, not so large as to seriously influence the resonance energy.
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