Abstract
Reaction of the nitronyl nitroxide radical NIT-C3H5 with Gd (hfac)3 affords a one-dimensional lanthanide–nitronyl nitroxide compound: [Gd (hfac)3 (NIT-C3H5)] n (1) Single crystal X-ray crystallographic analysis reveals that this compound is one-dimensional chain built up by Gd (hfac)3 units bridged by radicals through their NO groups. DC magnetic susceptibilities indicate that Gd complex paramagnetic above 2.0 K.
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