Abstract
Methane elimination during thermolysis of GaMe3 with PhHNNH2 yields sequentially dimeric [Me2Ga{µ-N(H)N(H)Ph}]2, tetrameric [MeGa{µ-N(H)NPh}]4 and, ultimately, GaN; the X-ray structure of the tetramer shows a novel Ga4N8 cage.
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