Abstract

In recent years, acid mine drainage (AMD) has emerged as a promising unconventional source of rare earth elements (REEs) and other critical minerals (CMs) such as cobalt and manganese. In this regard, AMD provides a natural heap leaching effect that extracts and concentrates REE/CM from the host strata creating a partially enriched feedstock suitable for downstream extraction, separation, and recovery. While several prior studies have described processes and approaches for the valorization of AMD, very few have described the supply chain and infrastructure requirements as well as the associated economic assessment. To that end, this paper provides a fundamental economic assessment of REE/CM recovery from AMD using a network sourcing strategy in addition to a robust, flexible feedstock separations and refining facility. The methodology of this paper follows that of a typical techno-economic analysis with capital and operating costs estimated using AACE Class IV (FEL-2) guidelines. To demonstrate the range of possible outcomes, four pricing scenarios were modeled including contemporary prices (September, 2021) as well as the minimum and maximum prices over the last decade. In addition, five production scenarios were considered reflecting variations in the product suite, ranging from full elemental separation to magnet REE and CM production only (i.e., Pr, Nd, Tb, Dy, Y, Sc, Co, and Mn). The results of this analysis show that, with the exception of the minimum price scenario, all operational configurations have positive economic indicators with rates of return varying from 25% to 32% for the contemporary price scenario. The optimal configuration was determined to be production of Co, Mn, and all REEs except for mischmetal, which is not recovered. Sensitivity analysis and Monte Carlo simulation show that capital cost and HCl consumption are the two major factors influencing rate of return, thus indicating opportunities for future technology development and cost optimization. Implications of the study and a cooperative profit-sharing model for sourcing are also described.

Highlights

  • Over the last decade, critical minerals have become an increasingly important matter of both technical and societal importance

  • This study addresses the economic potential of recovering critical minerals from acid mine drainage (AMD), a deleterious byproduct of many mining operations

  • The dispersed nature of rare earth elements (REEs) limits the economic potential of REE mining and as expected, most of the world production of LREEs and MREEs is generated as the by-product of iron mining at the Bayan Obo mine in northern China

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Summary

Introduction

Critical minerals have become an increasingly important matter of both technical and societal importance. An effective AMD treatment process was developed and patented by West Virginia University to recover REE and other critical minerals from AMD as a pre-concentrate using a two-step precipitation approach [45]. In this process, the AMD stream is first neutralized to a pH of 4 to 4.5 to precipitate all iron and most aluminum. The rare earth element and critical minerals recovery process used in this analysis was developed by L3Eng in collaboration with West Virginia University and Virginia Tech using pre-concentrate material generated by a patented two-step acid mine drainage (AMD) neutralization process [45]. The Hela Novel metals process utilizes a proprietary mixture of nitrogen, ammonia, carbon monoxide and hydrogen

Techno-Economic Analysis for the Recovery of REEs and CMs from AMD
Operating Cost Estimate
Capital Cost Estimate
Financial and Sensitivity Analysis
Financial Analysis
Implication of the Results
Findings
Conclusions
Full Text
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