Abstract
AbstractSynthesis and polymerization of N‐hexyl‐N‐[2‐(4‐vinylphenyl)ethyl]amine (5) are reported. To elucidate the reaction mechanism for the monomer synthesis, kinetic studies are carried out on the lithium catalyzed amination reaction of styrene (3) and of 1,4‐divinylbenzene (1) with hexylamine (2). The reaction rate, v, was found to be expressed as v = k [3] [2] [CH3(CH2)5NHLi], where k is the rate constant. Methods for selective synthesis of 5 are considered on the basis of results of the kinetic studies. Polymerization and copolymerization behavior of 5 shows that 5 has characteristics similar to 3 in radical polymerization.
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