Abstract

Explosives, especially those used for military weapons, have a short lifespan and their performance noticeably deteriorates over time. These old explosives need to be disposed of safely. Fluidized bed incinerators (FBIs) are safe for disposal of explosive waste (such as TNT) and produce fewer gas emissions compared to conventional methods, such as the rotary kiln. However, previous studies on this FBI process have only focused on minimizing the amount of NOx emissions without considering the operating and unitality costs (i.e., total cost) associated with the process. It is important to note that, in general, a number of different operating conditions are available to achieve a target NOx emission concentration and, thus, it requires a significant computational requirement to compare the total costs among those candidate operating conditions using a computational fluid dynamics simulation. To this end, a novel framework is proposed to quickly determine the most economically viable FBI process operating condition for a target NOx concentration. First, a surrogate model was developed to replace the high-fidelity model of an FBI process, and utilized to determine a set of possible operating conditions that may lead to a target NOx emission concentration. Second, the candidate operating conditions were fed to the Aspen Plus™ process simulation program to determine the most economically competitive option with respect to its total cost. The developed framework can provide operational guidelines for a clean and economical incineration process of explosive waste.

Highlights

  • Explosives are reacted under certain conditions to generate high energy; they have been used in various fields

  • For a target NOx emission concentration, among a set of operating conditions that may lead to the target, the one that requires a minimum cost was calculated by the surrogate model (Table 4)

  • This study aimed at providing a methodology to determine the optimal operating conditions for safe handling of the explosive waste via an Fluidized bed incinerators (FBIs) process at minimal capital and utility costs

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Summary

Introduction

Explosives are reacted under certain conditions to generate high energy; they have been used in various fields. They have been developed for military weapons with adequate quantities stockpiled for emergencies [1]. Explosives have a short lifespan and their performance noticeably deteriorates after 10 years, despite being stored in a suitable environment [2]. These old explosives are classified as explosive waste and are subject to disposal procedures. The main concerns regarding the incineration of explosive waste are safety and the reduction of the exhaust gas produced, which can be an environmental pollutant. Explosive waste must be carefully handled under stable conditions

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