Abstract
AbstractA formal total synthesis of iridoid 9‐deoxygelsemide has been accomplished. Our approach features the use of (S)‐carvone as starting material, Favorskii rearrangement to construct the functionalized cyclopentane core, Chugeav elimination to introduce the endocyclic double bond, and the ring‐opening reaction of epoxide to build the second five‐membered ring.
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