Abstract
Bridged-bicyclic tertiary allylic amines are proposed to react with isocyanates under Pd0-catalysis conditions to undergo a formal 1,3-diaza-Claisen rearrangement through a stepwise bond breaking and forming steps to afford bicyclic ureas. Additionally, N-benzyl azepine undergoes a formal Pd0-catalyzed 1,3-diaza-Claisen rearrangement with TsNCO to afford a 7-membered vinyl urea.
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