Abstract
A fluorescent three dimensional (3D) porous metal-organic framework {[Cd2(TPPE)(IPA)2]·2DMF}n (1) was synthesized by using a tetraphenylethene (TPE)-based ligand, 1,1,2,2‑tetrakis(4‑(pyridin‑4‑yl)phenyl)ethene (TPPE). The crystal structure, fluorescent emission in different solvents and fluorescent emission at different temperatures of complex 1 were studied, along with the aggregation induced emission (AIE) property of the organic ligand TPPE. This complex possesses intense blue luminescence and is sensitive to solvents. The luminescent emission intensity and peak wavelength both varied in different solvents. In addition, temperature-dependent emission spectrum of 1 exhibits regular variation. These properties of 1 possesses its potential applications in the fields of solvent sensing and luminescent thermometer.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.