Abstract
The air-stable complexes {(μ 4-TCNX)[Ru(NH 3) 5] 4}(PF 6) 8 which contain reduced TCNX ligands show spectroscopic equivalence of the four metal coordination sites on the 1H NMR and vibrational time scales and very close lying frontier orbitals (UV-Vis-NIR, electrochemistry). Both the two-electron oxidation behaviour and the magnetic moment of μ eff = 2.7 suggest a weak interaction between two mixed-valent malonodinitrilato/(Ru 2.5) 2 subsystems.
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