Abstract

We introduce a recent model of an isothermal, incompressible mixture of ionic species with finite ion size and solvation effects. A two point flux finite volume ansatz on unstructured meshes is chosen to discretize the model. Based on a reformulation of the continuous problem in terms of absolute activities, the Scharfetter-Gummel upwind scheme is generalized to take into account finite ion size and solvation effects in a thermodynamically consistent manner.

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