Abstract

In this paper, we present zinc oxide (ZnO)-based flexible harvesting devices employing commercially available, cost-effective thin aluminum (Al) foils as substrates and conductive bottom electrodes. From the device fabrication point of view, Al-foils have a relatively high melting point, allowing for device processing and annealing treatments at elevated temperatures, which flexible plastic substrate materials cannot sustain because of their relatively low melting temperatures. Moreover, Al-foil is a highly cost-effective, commercially available material. In this work, we fabricated and characterized various kinds of multilayered thin-film energy harvesting devices, employing Al-foils in order to verify their device performance. The fabricated devices exhibited peak-to-peak output voltages ranging from 0.025 V to 0.140 V. These results suggest that it is feasible to employ Al-foils to fabricate energy-efficient energy harvesting devices at relatively high temperatures. It is anticipated that with further process optimization and device integration, device performance can be further improved.

Highlights

  • With much progress in a variety of small-scale sensors, various energy harvesting technologies have been developed

  • Zinc oxide (ZnO), in particular, having a large piezoelectric constant has drawn much attention, since it can be deposited in the form of high-quality thin films [1]

  • Many research results have reported on various piezoelectric energy harvesters using polyethylene naphthalate (PEN), polyethylene terephthalate (PET), various metal wires, various flexible substrates, etc., in order to enhance the output voltages [8,9,10,11,12,13,14,15,16]

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Summary

Introduction

With much progress in a variety of small-scale sensors, various energy harvesting technologies have been developed. Lead-free ZnO is a nontoxic, environmentally friendly, and biocompatible material [2], it can be used to enable piezoelectric energy harvesters that are implanted into the body or in contact with the body skin. Lead-free ZnO-based piezoelectric energy harvesters produce lower output voltages than lead zirconate titanate (PZT)-based harvesters, containing toxic piezoelectric materials [7]. Various piezoelectric energy harvesters have been fabricated which exploit insulators to inhibit the so-called screening effect of free carriers, compensating for the positively polarized parts of ZnO, reducing the piezoelectric effect [7,8,11,13,14]. Mathematical analysis and simulation studies have been theoretically performed to evaluate and interpret the piezoelectric characteristics or phenomenon of piezoelectric materials and devices [18,19]

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