Abstract

Abstract In the presence of trityl perchlorate, 1-O-bromoacetyl-β-d-glucose stereoselectively reacts with alcohols to give the corresponding α-glucosides in good yields. The similar reaction of 1-O-acetyl-β-d-ribose affords the corresponding β-ribosides exclusively, while in the presence of molecular sieves 4A and lithium perchlorate, α-ribosides are prepared predominantly in good yields.

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