Abstract
The reaction of methyl 5-acetamido-4,7,8,9-tetra- O-acetyl-2-chloro-2,3,5-trideoxy-β- d- glycero- d- galacto-2-nonulopyranosonate with primary and secondary alcohols in the presence of silver salicylate affords, after O-deacetylation, stereo-specifically the corresponding methyl (alkyl 5-acetamido-3,5-dideoxy-α- d- glycero- d- galacto-2-nonulopyranosid)onates. The preparation of methyl(neopentyl 5-acetamido-3,5-dideoxy-α- d- glycero- d- galacto-2-nonulopyranosid)onate in benzene solution shows that this glycosylation can be carried out in an inert solvent.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
