Abstract

It's important to reduce recombination of electrons and holes and enhance charge transfer through fine controlled interfacial structure. In this work, novel graphitic-C3N4 (g-C3N4)/Ag2WO4/Ag ternary photocatalyst has been synthesized by deposition of Ag2WO4 onto g-C3N4 template and followed by sun light reduction of Ag2WO4 into Ag2WO4/Ag. As-prepared g-C3N4/Ag2WO4/Ag presented significantly enhanced photocatalytic performance in degrading methylene blue (MB) under 410 nm LED light irradiation. Metallic Ag0 is used as plasmonic hot spots to generate high energy charge carriers. Optimal g-C3N4 content has been confirmed to be 40 wt%, corresponding to apparent pseudo-first-order rate constant kapp of 0.0298 min−1, which is 3.3 times and 37.3 times more than that of pure g-C3N4 and Ag2WO4, respectively. This novel ternary g-C3N4/Ag2WO4/Ag structure material is an ideal candidate in environmental treatment and purifying applications.

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