A facile decoration of anatase Fe3O4/TiO2 nanocomposite with graphene quantum dots: Synthesis, characterization, and photocatalytic activity

Abstract

A combination of electron-rich graphene quantum dots (GQDs) with Fe3O4/TiO2 nanocomposites may develop an efficient electron transfer for enhanced photocatalytic activity. In this report, a facile decoration of GQDs with maltose precursor was synthesized and loaded onto magnetic anatase TiO2 nanocomposites under hydrothermal methods. The as-synthetized magnetic TiO2/GQDs nanocomposite resulted in a specific surface area of 38.00 m2/g and a total pore volume of 0.186 cm3/g. The HRTEM images showed a lattice plane distance of 0.350 nm related to the interplanar spacing of the anatase TiO2 (101) plane and that of 0.299 nm observed for the in-plane lattice part of GQDs. The effects of magnetic loading ratio and GQDs loading onto TiO2, pH, photocatalyst dosage, and methylene blue (MB) concentration were thoroughly evaluated to find the optimum conditions of mineralization MB for getting the highest photocatalytic efficiency. The removal efficiency of around 86.08 ± 3.62% was obtained at pH11, photocatalytic dose 400 mg/100 mL, and MB concentration 10 mg/L. Moreover, the photogenerated electron transfers and MB degradation mechanism by the resulting Fe3O4/TiO2/GQDS under irradiation of UVA light are proposed. The as-synthesized material improved meaningfully greater photocatalytic efficiency for degrading MB under UVA light irradiation than merely pure anatase TiO2. Also, the predominant mechanism of MB degradation was direct oxidative decomposition through the photogenerated holes. The photocatalytic destruction of MB complied with the apparent first-order models under UVA light irradiation.