Abstract
Like a sponge: Soft, three-dimensional, porous coordination frameworks {[Ln(tci)⋅H2O]⋅4 H2O}n (Ln=Ce, Gd; tciH3=tris(2-carboxyethyl)isocyanurate] were prepared from Ln(NO3)3⋅x H2O and tciH3. The flexible arms and secondary functional groups of the ligand allow the framework to show spongelike dynamic behavior such as selective and stepwise adsorption, associated with single crystal to single crystal structural transformation (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z705986_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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