A domain decomposition method for a two‐phase transport model of polymer electrolyte fuel cell containing micro‐porous layer

Abstract

SUMMARYIn this paper, a nonlinear Dirichlet–Robin iteration‐by‐subdomain domain decomposition method is studied for a multidimensional, multiphysics, and multiphase model of polymer electrolyte fuel cell (PEFC) containing micro‐porous layer (MPL). Across the interface of gas diffusion layer and MPL in PEFC, it is well known that the capillary pressure is continuous, whereas liquid saturation is discontinuous, by which the liquid‐water removal in the porous electrodes can be significantly enhanced. We design a type of non‐overlapping domain decomposition method to deal with water transport in such multi‐layer diffusion media, where Kirchhoff transformation and its inverse techniques are employed to conquer the discontinuous and degenerate water diffusivity in the coexisting single‐phase and two‐phase regions. In addition, the conservation equations of mass, momentum, charge, and hydrogen and oxygen transport are also solved by the combined finite element–upwind finite volume method (FEM/FVM) to overcome the dominated convection effect in gas channels. Numerical simulations demonstrate that the presented techniques are effective in obtaining a fast and convergent nonlinear iteration for such a 3D PEFC model within around 50 steps, in contrast with the oscillatory and nonconvergent iteration conducted by standard FEM/FVM. A series of numerical convergence tests are also carried out to verify the efficiency and accuracy of the present numerical techniques. Copyright © 2012 John Wiley & Sons, Ltd.