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Abstract
We present the structure elucidation of a copper(I) complex of a monoanionic phosphanylalkyl-diimido sulfonate ligand centered by a sulfur-copper cube. It has the formula [{Me2PCH2S(NSiMe3)2}4 Cu8{CuS}4] (2) and is the first example of a copper(I) complex of this new ligand type.
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