A dithioxo-bishydroxylaminomolybdenum complex as sulfur and nitrogen transfer reagent. Synthesis of thioureas from isonitriles

Janice J Byrne,Yannick Vallée

doi:10.1016/s0040-4039(98)02418-6

A dithioxo-bishydroxylaminomolybdenum complex as sulfur and nitrogen transfer reagent. Synthesis of thioureas from isonitriles

Janice J Byrne, Yannick Vallée

https://doi.org/10.1016/s0040-4039(98)02418-6

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Journal: Tetrahedron Letters	Publication Date: Jan 1, 1999
Citations: 10

#Nitrogen Transfer Reagent #Synthesis Of Thioureas + Show 5 more

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Abstract

Cis-dithioxo-bis(( N,N-diethyl)hydroxylamido(1-)- O,N)molydenum(VI) reacts with isonitriles to give the corresponding N,N-diethylthioureas. A mechanism is proposed for this S,N-transfer reaction.

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