Abstract
AbstractThe tetranuclear nickel cluster {[Ni4(L)4(C2H5OH)4]·7H2O} (1) was synthesized based on the tridentate Schiff base ligand H2L = 1‐phenyl‐3‐[(2‐hydroxyphenyl)imino]‐1‐butanone. The structure of 1 was determined by single‐crystal X‐ray diffraction. It exhibits a discrete [Ni4O4] cluster. Magnetic studies indicate that ferromagnetic interactions exist within compound 1. Furthermore, thermogravimetric analysis and PXRD patterns in various solvents reveal thermal and solvent stability of compound 1.
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