Abstract
Detecting the partial discharge in gas-insulated switchgear (GIS) equipment by detecting the type and concentration of SF6 characteristic decomposition products is very important and effective in ensuring the regular operation of GIS equipment. In this study, VTi-Ti3C2O2 (Ti-deficient Ti3C2O2) and TM-doped (TM = Ti, Pt, Au) α-type Ti3C2O2 were carried out as the gas-sensing materials. The gas adsorption structures of SO2, SOF2, and SO2F2 on the surfaces of TM-modified Ti3C2O2 were established. Different adsorption systems' adsorption energies, electron densities, state densities, and times for gas desorption were examined using DFT calculations. Following the analysis, physical adsorption of SO2, SOF2, and SO2F2 occurs on the surface of Pt-Ti3C2O2 and Au-Ti3C2O2, while chemical adsorption occurs on the surface of VTi-Ti3C2O2. As a result, it is challenging to remove the gas molecules from the surface of VTi-Ti3C2O2, while it is simple to remove them from Pt-Ti3C2O2 and Au-Ti3C2O2 surfaces. At the same time, compared with gas adsorption on the surface of pristine Ti3C2O2, TM-modified Ti3C2O2 can improve the adsorption performance of pristine Ti3C2O2 on the characteristic decomposition products of SF6 to a certain extent.
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