Abstract

An analysis of NMR lineshapes and spin-lattice relaxation times for the 2H nucleus is reported for the liquid and solid phases I, II, and III of (CD 3) 3CBr. The main results are a discontinuous increase of the rotational correlation time on melting (with a concomitant increase of the Arrhenius parameter) and, for phase II, a demonstration of the feasibility of measuring order parameters on the different timescales probed by the absorption profile and the relaxation experiment.

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