Abstract

33S magnetic resonance spectra have been obtained as a function of temperature for neat liquid carbon disulfide, and the 33S quadrupole coupling constant e 2qQ h = 14.9 ± 0.3 MHz has been determined from the linewidth using previously reported reorientational correlation times. The molecular reorientation of CS 2 is discussed in terms of current hydrodynamic models for molecular reorientation in liquids.

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