Abstract
The first azido-bridged mixed-valent cobalt defective double cubane cluster complex was synthesized and characterized structurally and magnetically. The new azido-bridged cobalt cluster complex, [ Co 2 II Co 2 III μ 1 , 1 - N 3 ) 4 ( N 3 ) 2 ( HDMSP ) 2 ( MeOH ) 2 ] · 2 H 2 O (H 3 DMSP = 1,3-dihydroxy-2-methyl-2-(salicylideneamino)propane), is the first azido-bridged mixed-valent cobalt complex showing a defective double cubane structure. Magnetic study indicated that there is an antiferromagnetic interaction between two Co 2+ ions.
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