A database of fluctuation thermodynamic properties and molecular correlation function integrals for a variety of binary liquids

Abstract

Wooley R.J. and O'Connell J.P., 1991. A database of fluctuation thermodynamic properties and molecular correlation function integrals for a variety of binary liquids. Fluid Phase Equilibria, 66: 233-261. Literature data on fluctuation thermodynamic properties have been analyzed to establish a reliable database of fluctuation properties (reduced bulk modulus, and concentration derivatives of the pressure and activity coefficient) and direct and total correlation function integrals for 26 binary non-electrolyte liquid solutions saturated at fixed temperatures. These values may be useful for comparisons with molecular theories, solution model and equation-of-state parameter mixing rules, and for verifying experimental data from light scattering and equilibrium ultracentrifuge sedimentation.