Abstract
The chloro-bridged cyclometallated palladium(II) complex [PdCl{κC,Se-C6H4P(Se)Ph2}]2 reacts with 4-MeC6H4C(O)NHC(Se)NEt2 in the presence of base to give [Pd{κC,Se-C6H4P(Se)Ph2}{κO,Se-4-MeC6H4C(O)NC(Se)NEt2}] in high yield. The complex was fully characterised by spectroscopic methods and also X-ray diffraction. This compound represents one of the few examples of a metal complex containing two different selenium-containing ligands.
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