A cyclone reactor of electrochemical advanced oxidation processes using PbO2 anode and H2O2 electrosynthesis cathode

Abstract

Electrochemical advanced oxidation processes are promising tools for pollution abatement but most still lack practical engineering attempts and devices. A type of process intensification reactor for the electrochemical advanced oxidation processes is developed here. The cyclone continuous flow electrochemical reactor adopts a PbO2 anode and H2O2 electrosynthesis cathode together. A lab-scale cyclone continuous flow electrochemical reactor is fabricated and simulated, which is evaluated using the H-acid wastewater. The contributions of the PbO2 anode and H2O2 electrosynthesis cathode to pollutant degradation are discussed particularly. A 3-D model is developed to provide a visualized perspective on the reactor performances, including flow distribution, mass transfer, and current distribution. Pronounced signals of powerful radicals can be detected for the PbO2H2O2 cyclone reactor, including •OH, SO4•−, and 1O2. It exhibits excellent performances on mass transfer, electrical properties, organic degradation, and space-time yield. Such a strategy presents a promising engineering solution for scale-up and further development toward industrial application.