Abstract
A cyclic octameric water cluster is trapped in a 3-D supramolecular architecture [Cu2(H2O)2(bpca)2L]8H2O, where bpca = bis(2-pyridylcarbonyl)amide and L = sebacic acid. The striking feature of the octameric cluster is that each water donates one hydrogen to adjacent waters to form a circular water ring in a (O–HO–H)4 connecting fashion, with the same orientations of OH bonds in the ring. Thermogravimetric and magnetic properties are also reported.
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