Abstract
AbstractA soluble cyclic porphyrin oligomer (CPO) consisting of four 5,10‐diarylporphyrins linked by alternating azo and butadiyne bridges has been synthesised via an aminated dinickel(II) butadiyne dimer. This is the first cyclic tetramer that combines both azo and butadiyne bridges and extends the azoporphyrin family, which comprises only a very few examples. The electronic absorption spectrum of the tetramer is more similar to spectra of azoporphyrins than to those of butadiyne‐linked dimers or tetramer, exhibiting a two‐component Soret band with a splitting of 4190 cm–1 and a strongly red‐shifted Q band maximum at 735 nm.
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