Abstract
Environmental and temperature effects on the absorption spectrum of Ru(CN) 4− 6 ion in solution were used to detect the existence of a charge transfer to solvent (CTTS) band. The salt and solvent effects were related to the theory dealing with the environmental effects on CTTS bands of polyvalent ions. The formation of hydrated electrons from the photoexitation of the Ru(CN) 4− 6 in aqueous solutions was attributed to the involvement of the CTTS excited state.
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