Abstract
The compound bis(ethylenediamine- N , N ′)-(oxalato- O , O ′)-cobalt biphenyl-4,4′-disulfonate hydrate, refcode TIQHOR, crystallizes with four Co(III) cations in the asymmetric unit. Another pair of compounds, rac-bis(ethylenediamine- N , N ′)-(oxalato- O , O ′)-cobalt(III) l -hydrogenaspartate, refcode VAGBOU, and tetra-ammine-( N -benzylethanediamine)-cobalt(III) trinitrate sesquihydrate, refcode ZIFHEB crystallize both as conglomerates and kryptoracemates. Their stereochemical characteristics are described, and the fact that they display more than one mode of crystallization in a single lattice, is illustrated numerically and visually.
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