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Abstract
The i.r. spectra of several new carbonato complexes of cobalt(III) are reported and it has been found that the bridging carbonato ligand can be distinguished from the bidentate species and possibly from the monodentate species. By comparing available X-ray structural and i.r. spectral data for a large variety of carbonato complexes a strong correlation has been found between the angular distortion (from D 3 h ) within the carbonato ligand and the separation between the two highest energy CO stretching modes.
Published Version
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Schedule a callMore From: Spectrochimica Acta Part A: Molecular Spectroscopy
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