A Coral Reef-like Structure Fabricated on Cellulose Paper for Simultaneous Oil-Water Separation and Electromagnetic Shielding Protection.

Abstract

The functional design of paper-based material surfaces with renewable functions and environmentally friendly properties is prevalent nowadays. Herein, a superhydrophobic surface with a coral reef-like structure was prepared on filter paper by electroless copper plating, rapid silver nitrate etching, and facile 1-hexadecanethiol impregnation. After low-surface-energy thiol treatment, this unique coral reef-like structure surface showed excellent superhydrophobicity with a water contact angle of 163.8° and superoleophobicity with an oil contact angle of 0°, which could be used for oil–water separation and had a separation efficiency above 89.17% after 12 consecutive oil–water separations. Because the copper layer and silver nanostructure are both excellent conductive materials, the modified paper exhibited excellent electromagnetic shielding properties, and the electromagnetic interface shielding effectiveness exceeded 63 dB from 9 kHz to 1.5 GHz. The modified paper also had excellent self-cleaning properties and a better corrosion resistance. The unique three-dimensional interweaving structure between the cellulose fibers in the filter paper is fully utilized, and the substitution reaction between the silver ion and the copper coating produces a coral reef-like structure, which provides a new strategy for promoting the wide application of paper-based materials.