Abstract
Amidated and deamidated chiral DAP- d -Ala analogues were prepared by olefin cross-metathesis of 12 with modified d -allylglycines using Grubbs’ 2nd generation catalyst. Hydrogenation and deprotection of these precursors provided four chiral (2S,6R)-DAP- d -alanine derivatives that were examined as substrates for Mtb l , d -transpeptidases in a 14C- d -Ala exchange reaction.
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