Abstract
AbstractA short enantioselective synthesis of phoracantholide I [(R)‐4] (ee = 91 %), a component of the defensive secretion of the eucalypt longicorn Phoracantha synonyma, is described. Key steps of the synthesis are the enantioselective α‐alkylation of cyclononanone SAMP hydrazone [(S)‐1] (de > 93%) and subsequent Baeyer‐Villiger reaction of the ketone (R)‐3 with retention of configuration.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
