Abstract

AbstractThis paper is the first part of a work that aims at developing a mechanical model for the behaviour of propellant‐like materials under high confining pressure and strain rate. The behaviour of a typical material is investigated experimentally. Several microstructural deformation processes are identified and correlated with loading conditions. The resulting behaviour is complex, non‐linear, and characterized by multiple couplings. The general structure of a relevant model is sought using a thermodynamic framework. A viscoelastic‐viscoplastic‐compaction model structure is derived under suitable simplifying assumptions, in the framework of finite, though moderate, strains. Model development, identification and numerical applications are given in the companion paper. Copyright © 2001 John Wiley & Sons, Ltd.

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