Abstract

AbstractA constitutive equation has been developed to relate surface stresses to the deformational history of an interface. This equation is designed to provide a unified description of complex interfacial rheological phenomena. New and as yet unreported behavior such as surface normal stresses and viscoelastic contributions to the dynamic surface tension are predicted.A monolayer of poly(vinyl alcohol) adsorbed at an air/water interface has been studied using a deep channel surface rheometer and the observed viscoelastic behavior shown to be fitted by the model.

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