Abstract
Abstract The trans influence of three ligands (OH−, Cl−, and H2O) was compared for the first time according to the same experimental standard (1J(PtPtrans)). Based on the extremely high trans influence of the OH− ligand, a mechanism was proposed for the palladium(II) oxidation of ethylene, which includes the rate-determining external attack of H2O on a possible intermediate, trans-[PdCl2(OH)(C2H4)]−.
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