A conical spiral methanol steam reforming reactor for spectral splitting-based concentrating photovoltaic-thermochemical hybrid production

Abstract

Listen

Translate article

The spectral beam splitting (SBS) photovoltaic-thermochemical hybrid system improves the solar thermal energy grade through photon energy cascade distribution and methanol steam reforming (MSR) reaction. Given the deficiency of MSR reactor development for dish-concentrating SBS systems, the conical spiral structure is introduced to the receiver/reactor in this work, thus facilitating efficient absorption of circular beams and ameliorating the adaptability of the production. Based on specially designed spectral beam splitter, the Monte Carlo ray tracing (MCRT) method is employed to simulate the non-imaging optical process and optimized reflective cone structure. Thermodynamics and kinetic models of the reactor are established and experimentally validated. The analysis results show that the reflective cone advances the optical efficiency of the reactor to 76.95%, and the conical spiral structure helps to enhance heat and mass transfer for utilization of the catalytic space. The mid/low-temperature reaction prefers a solution flow rate of less than 1.53 mL s−1 and a water-methanol ratio of 1.4–1.9, with the maximum solar thermochemical conversion rate of 54.5%. Moreover, the upgrading in photothermal and photovoltaic heat exceeds respectively 0.62 and 8.97 at less than 600 W m−2 of irradiation, demonstrating the adaptive potential of the reactor. In summary, the research results contribute to broadening the operating conditions of the hybrid production and the full-spectrum penetration of solar energy in distributed scenarios.