Abstract
AbstractShort and efficient formal syntheses of (2R,3R)‐ and (2R,3S)‐3‐hydroxypipecolic acids, and total syntheses of (–)‐deoxoprosopinine and (+)‐2‐epi‐deoxoprosopinine have been achieved starting from D‐glycals. The key steps involved in these syntheses were Ferrier rearrangement, azide reduction, intramolecular cyclization, and Grignard reaction.
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