A Computational Study of the Mass Transport Behavior of Hydrogen in In-Service Carbon Steel Pipeline Fillet Welds During Deposition and Desorption

Abstract

Numerical calculations were used to study the diffusion and thermotransport of hydrogen during deposition and diffusion of hydrogen during desorption of in-service carbon steel pipeline fillet welds prone to hydrogen cracking. During deposition, only a small amount of hydrogen migrates into the HAZ and little migrates into the pipe. Thermotransport decreases the hydrogen concentration in the HAZ and regions of the weld closer to the HAZ, and increases the concentration toward the outer edge of the weld. This effect increases the rate of desorption of hydrogen from the weld, which increases with weld size/pipe wall thickness. The activation energy for desorption varies with the fraction of hydrogen removed and appears to be a function of the activation energy for diffusion and mass fraction of hydrogen in the weld, HAZ, and pipe. The differences in the desorption rate due to thermotransport appear to be due to differences in the activation energy for desorption and hydrogen concentration gradients. Maintaining a 121 °C preheat/interpass temperature during welding significantly reduces post-weld heating times necessary to reach hydrogen levels considered to be safe from hydrogen cracking. Calculated results and experimental results from another study show good agreement for desorption at 132 °C for up to 30 minutes.