Abstract

AbstractThe lunar exosphere is an ensemble of multiple overlapping, noninteracting neutral distributions that reflect the primary physical processes acting on the lunar surface. While previous observations have detected and constrained the behavior of some species, many others have only circumstantial evidence or theoretical modeling suggesting their presence. Many species are so tenuous as to be unobservable by direct neutral sampling, yet in comparison, measurements in their ionized form provide a particularly sensitive method of detection. To better aid the interpretation of past measurements and planning of future observations, we present a model for the production of lunar pickup ions from the Moon consisting of two components: An analytic model for the distributions of 18 neutral species produced by various mechanisms and an analytic model for the ionization and subsequent acceleration of 20 exospheric and surface‐sputtered pickup ion species. The dominant lunar pickup ions in the model are , He+, CO+, 40Ar+, Al+, Na+, K+, Si+, Ca+, and O+ with an asymmetric distribution favoring the positive interplanetary electric field hemisphere of the Moon. We compare the model predictions to statistically averaged pickup ion fluxes around the Moon as observed by the ARTEMIS spacecraft over the past decade. By filtering for interplanetary electric field‐aligned, high‐energy observations, we find that the pickup ion model lacks an additional source of heavy species. We suggest that a dense CO2 exosphere of 3 × 104 − 1 × 105 cm−3 could account for the missing pickup ion flux as part of the recycling of solar wind carbon ions incident to the Moon.

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