Abstract
Complex ZnLCl2·EtOH·H2O (I) where L is chiral 9,9′-bi-4,5-diazafluorenylidene containing fragments of natural monoterpenoide (–)-α-pinene is synthesized. The crystal structure of I is composed of ZnLCl2 mononuclear complex, solvate EtOH, and H2O molecules. The coordination polyhedron Cl2N2 of the Zn atom is a distorted tetrahedron. L is a bidentate cyclic ligand, involving only two N atoms in the coordination. Complex I is characterized by IR and NMR spectroscopy and its thermal properties are analyzed. In the solid phase, L exhibits photoluminescence is the visible range (λmax = 610 nm).
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