Abstract

In the present short communication, the diagrammatic many-body perturbation theory for the rederivation of PCILO method (perturbation configuration interaction using localized orbitals, see Theoret. Chim. Acta (Berl.)13, 1 (1969) and15, 100 (1969)) is consequently used. Using the Goldstone-Hugenholtz linked-cluster theorem, the diagrammatic expression for the exact ground-state energy is obtained. An application of the present approach to the low-lying excited and/or ionized states is also discussed.

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